N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction
Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in
Beilstein J. Org. Chem. 2023, 19, 1841–1848.
https://doi.org/10.3762/bjoc.19.136
Chemical Information
Calculated using the Chemistry Development Kit 2.12
| Molecular Formula | C20H24N2O5 |
| Molecular Weight | 372.42 g/mol |
| Exact Mass | 372.1685 Da |
| InChI |
InChI=1S/C20H24N2O5/c1-12(23)13-5-6-15-14(11-13)9-10-21(15)16-7-8-17(24)22(18(16)25)19(26)27-20(2,3)4/h5-6,11,16H,7-10H2,1-4H3
|
| InChIKey |
HDNLRHCIZBTFDZ-UHFFFAOYSA-N
|
| SMILES |
CC(=O)C1=CC=C2C(=C1)CCN2C3CCC(=O)N(C3=O)C(=O)OC(C)(C)C
|
| Number of Atoms | 51 |
| Number of H-Bond Acceptors | 7 |
| Number of H-Bond Donors | 0 |
| Atoms in the Largest π-System | 9 |
| XLogP | 1.7 |