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N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in

Beilstein J. Org. Chem. 2023, 19, 1841–1848. https://doi.org/10.3762/bjoc.19.136

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Chemical structure C<sub>16</sub>H<sub>17</sub>N<sub>5</sub>O<sub>6</sub>

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Extracted from

Scheme 3 Scheme 5

Chemical Information

Calculated using the Chemistry Development Kit 2.12

Property Name	Property Value
Molecular Formula	C₁₆H₁₇N₅O₆
Molecular Weight	375.34 g/mol
Exact Mass	375.1179 Da
InChI	InChI=1S/C16H17N5O6/c1-16(2,3)27-15(24)19-12(22)8-7-11(14(19)23)20-17-9-5-4-6-10(21(25)26)13(9)18-20/h4-6,11H,7-8H2,1-3H3
InChIKey	LMWBNEYKZTVAIL-UHFFFAOYSA-N
SMILES	CC(C)(C)OC(=O)N1C(=O)CCC(C1=O)N2N=C3C=CC=C(C3=N2)[N+](=O)[O-]
Number of Atoms	44
Number of H-Bond Acceptors	8
Number of H-Bond Donors	0
Atoms in the Largest π-System	12
XLogP	2.1

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