N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in
Beilstein J. Org. Chem. 2023, 19, 1841–1848. https://doi.org/10.3762/bjoc.19.136

Chemical Information

Calculated using the Chemistry Development Kit 2.12
Molecular Formula C10H12BrN3O2
Molecular Weight 286.13 g/mol
Exact Mass 285.0113 Da
InChI
InChI=1S/C10H12BrN3O2/c1-5-9(11)6(2)14(13-5)7-3-4-8(15)12-10(7)16/h7H,3-4H2,1-2H3,(H,12,15,16)
InChIKey
LTDOBSUFPLKOCL-UHFFFAOYSA-N
SMILES
CC1=NN(C(=C1Br)C)C2CCC(=O)NC2=O
Number of Atoms 28
Number of H-Bond Acceptors 5
Number of H-Bond Donors 1
Atoms in the Largest π-System 5
XLogP 0.9
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