N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction
Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in
Beilstein J. Org. Chem. 2023, 19, 1841–1848.
https://doi.org/10.3762/bjoc.19.136
Chemical Information
Calculated using the Chemistry Development Kit 2.12
| Molecular Formula | C25H25N3O4 |
| Molecular Weight | 431.48 g/mol |
| Exact Mass | 431.1845 Da |
| InChI |
InChI=1S/C25H25N3O4/c1-25(2,3)32-24(31)27-22(29)15-14-20(23(27)30)28-21(18-12-8-5-9-13-18)16-19(26-28)17-10-6-4-7-11-17/h4-13,16,20H,14-15H2,1-3H3
|
| InChIKey |
POTJIJFKKHQWGK-UHFFFAOYSA-N
|
| SMILES |
CC(C)(C)OC(=O)N1C(=O)CCC(C1=O)N2C(=CC(=N2)C3=CC=CC=C3)C4=CC=CC=C4
|
| Number of Atoms | 57 |
| Number of H-Bond Acceptors | 7 |
| Number of H-Bond Donors | 0 |
| Atoms in the Largest π-System | 17 |
| XLogP | 3.7 |
