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N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in

Beilstein J. Org. Chem. 2023, 19, 1841–1848. https://doi.org/10.3762/bjoc.19.136

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Chemical structure C<sub>20</sub>H<sub>27</sub>N<sub>3</sub>O<sub>6</sub>S

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Extracted from

Scheme 3

Chemical Information

Calculated using the Chemistry Development Kit 2.12

Property Name	Property Value
Molecular Formula	C₂₀H₂₇N₃O₆S
Molecular Weight	437.51 g/mol
Exact Mass	437.1620 Da
InChI	InChI=1S/C20H27N3O6S/c1-20(2,3)29-19(26)23-17(24)9-8-16(18(23)25)22-11-10-13-12-14(6-7-15(13)22)30(27,28)21(4)5/h6-7,12,16H,8-11H2,1-5H3
InChIKey	QTYGSICVRSFJEW-UHFFFAOYSA-N
SMILES	CC(C)(C)OC(=O)N1C(=O)CCC(C1=O)N2CCC3=CC(=CC=C32)S(=O)(=O)N(C)C
Number of Atoms	57
Number of H-Bond Acceptors	9
Number of H-Bond Donors	0
Atoms in the Largest π-System	11
XLogP	0.9

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