N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in
Beilstein J. Org. Chem. 2023, 19, 1841–1848. https://doi.org/10.3762/bjoc.19.136

Chemical Information

Calculated using the Chemistry Development Kit 2.12
Molecular Formula C14H14N4O3
Molecular Weight 286.29 g/mol
Exact Mass 286.1066 Da
InChI
InChI=1S/C14H14N4O3/c1-7-16-9-4-2-3-8(15)12(9)14(21)18(7)10-5-6-11(19)17-13(10)20/h2-4,10H,5-6,15H2,1H3,(H,17,19,20)
InChIKey
RSNPAKAFCAAMBH-UHFFFAOYSA-N
SMILES
CC1=NC2=C(C(=CC=C2)N)C(=O)N1C3CCC(=O)NC3=O
Number of Atoms 35
Number of H-Bond Acceptors 7
Number of H-Bond Donors 2
Atoms in the Largest π-System 12
XLogP -1.3
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