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N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in

Beilstein J. Org. Chem. 2023, 19, 1841–1848. https://doi.org/10.3762/bjoc.19.136

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Chemical structure C<sub>16</sub>H<sub>18</sub>N<sub>4</sub>O<sub>4</sub>

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Extracted from

Scheme 3

Chemical Information

Calculated using the Chemistry Development Kit 2.12

Property Name	Property Value
Molecular Formula	C₁₆H₁₈N₄O₄
Molecular Weight	330.34 g/mol
Exact Mass	330.1328 Da
InChI	InChI=1S/C16H18N4O4/c1-16(2,3)24-15(23)19-13(21)9-8-12(14(19)22)20-11-7-5-4-6-10(11)17-18-20/h4-7,12H,8-9H2,1-3H3
InChIKey	SCSKCYZDVXQFRM-UHFFFAOYSA-N
SMILES	CC(C)(C)OC(=O)N1C(=O)CCC(C1=O)N2C3=C(C=CC=C3)N=N2
Number of Atoms	42
Number of H-Bond Acceptors	8
Number of H-Bond Donors	0
Atoms in the Largest π-System	9
XLogP	1.0

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