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N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in

Beilstein J. Org. Chem. 2023, 19, 1841–1848. https://doi.org/10.3762/bjoc.19.136

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Chemical structure C<sub>19</sub>H<sub>23</sub>BrN<sub>2</sub>O<sub>4</sub>

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Extracted from

Scheme 3

Chemical Information

Calculated using the Chemistry Development Kit 2.12

Property Name	Property Value
Molecular Formula	C₁₉H₂₃BrN₂O₄
Molecular Weight	423.30 g/mol
Exact Mass	422.0841 Da
InChI	InChI=1S/C19H23BrN2O4/c1-19(2,3)26-18(25)22-16(23)9-8-15(17(22)24)21-10-4-5-12-11-13(20)6-7-14(12)21/h6-7,11,15H,4-5,8-10H2,1-3H3
InChIKey	TXPXTNZKOTZICR-UHFFFAOYSA-N
SMILES	CC(C)(C)OC(=O)N1C(=O)CCC(C1=O)N2CCCC3=CC(=CC=C32)Br
Number of Atoms	49
Number of H-Bond Acceptors	6
Number of H-Bond Donors	0
Atoms in the Largest π-System	8
XLogP	3.0

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