N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction
Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in
Beilstein J. Org. Chem. 2023, 19, 1841–1848.
https://doi.org/10.3762/bjoc.19.136
Chemical Information
Calculated using the Chemistry Development Kit 2.12
| Molecular Formula | C19H19F3N4O6 |
| Molecular Weight | 456.37 g/mol |
| Exact Mass | 456.1257 Da |
| InChI |
InChI=1S/C19H19F3N4O6/c1-18(2,3)32-17(30)25-14(27)7-6-13(15(25)28)26-23-11-5-4-10(8-12(11)24-26)16(29)31-9-19(20,21)22/h4-5,8,13H,6-7,9H2,1-3H3
|
| InChIKey |
XLXPYKVAKIOUEZ-UHFFFAOYSA-N
|
| SMILES |
CC(C)(C)OC(=O)N1C(=O)CCC(C1=O)N2N=C3C=CC(=CC3=N2)C(=O)OCC(F)(F)F
|
| Number of Atoms | 51 |
| Number of H-Bond Acceptors | 10 |
| Number of H-Bond Donors | 0 |
| Atoms in the Largest π-System | 12 |
| XLogP | 3.1 |
