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Catalytic aza-Nazarov cyclization reactions to access α-methylene-γ-lactam heterocycles

Bilge Banu Yagci, Selin Ezgi Donmez, Onur Şahin and Yunus Emre Türkmen

Beilstein J. Org. Chem. 2023, 19, 66–77. https://doi.org/10.3762/bjoc.19.6

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Chemical structure [C<sub>20</sub>H<sub>30</sub>NOSi]<sup>+</sup>

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Extracted from

Scheme 9

Chemical Information

Calculated using the Chemistry Development Kit 2.12

Property Name	Property Value
Molecular Formula	[C₂₀H₃₀NOSi]⁺
Molecular Weight	328.54 g/mol
Exact Mass	328.2097 Da
InChI	InChI=1S/C20H30NOSi/c1-16(2)10-11-19(15-23(3,4)5)20(22)21-13-12-17-8-6-7-9-18(17)14-21/h6-9,11,14,16H,10,12-13,15H2,1-5H3/q+1/b19-11-
InChIKey	CQIQETZHHWHRCN-ODLFYWEKSA-N
SMILES	CC(C)C/C=C(/C[Si](C)(C)C)\C(=O)[N+]1=CC2=C(C=CC=C2)CC1
Number of Atoms	53
Number of H-Bond Acceptors	1
Number of H-Bond Donors	0
Atoms in the Largest π-System	12
XLogP	4.8

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