Pd-Catalyzed asymmetric allylic amination with isatin using a P,olefin-type chiral ligand with C–N bond axial chirality

Natsume Akimoto, Kaho Takaya, Yoshio Kasashima, Kohei Watanabe, Yasushi Yoshida and Takashi Mino
Beilstein J. Org. Chem. 2025, 21, 1018–1023. https://doi.org/10.3762/bjoc.21.83

Supporting Information

Data of thermal racemization of 7, DFT calculations for investigating racemization mechanism of 7, general methods and materials, experimental procedures and characterization data, 1H, 13C and 31P NMR spectra for 9 and 10, 1H, 13C and 31P NMR spectra and HPLC charts for (±)-7, (+)-7 and (–)-7, 1H and 13C NMR spectra and HPLC charts for (S)-13ak (except (S)-13e) and (S)-16.

Supporting Information File 1: Experimental section and compounds characterization.
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Cite the Following Article

Pd-Catalyzed asymmetric allylic amination with isatin using a P,olefin-type chiral ligand with C–N bond axial chirality
Natsume Akimoto, Kaho Takaya, Yoshio Kasashima, Kohei Watanabe, Yasushi Yoshida and Takashi Mino
Beilstein J. Org. Chem. 2025, 21, 1018–1023. https://doi.org/10.3762/bjoc.21.83

How to Cite

Akimoto, N.; Takaya, K.; Kasashima, Y.; Watanabe, K.; Yoshida, Y.; Mino, T. Beilstein J. Org. Chem. 2025, 21, 1018–1023. doi:10.3762/bjoc.21.83

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