Ring opening metathesis polymerization-derived block copolymers bearing chelating ligands: synthesis, metal immobilization and use in hydroformylation under micellar conditions

Gajanan M. Pawar, Jochen Weckesser, Siegfried Blechert and Michael R. Buchmeiser

Beilstein J. Org. Chem. 2010, 6, No. 28. https://doi.org/10.3762/bjoc.6.28

Supporting Information

Supporting Information contains polymerization kinetics of M1 by the action of Mo(N-2,6-Me2 C6H3)(CHCMe2Ph)(OCMe(CF3)2)2, GPC-traces (DMF) of poly(M1) and poly(M1-b-M2); cmc measurements for poly(M1-b-M2) and poly(M1-b-M2)-Rh in water; conversion of 1-octene, product formation, product distribution in the hydroformylation of 1-octene in toluene in the presence of C1, C1 and triphenylphosphite; n:iso selectivities for catalysts poly(M1-b-M2)-Rh) and poly(M1-b-M2)-Rh with triphenylphosphite as a function of conversion.

Supporting Information File 1: Graphical representations of measurements.
Format: PDF Size: 360.0 KB Download

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