Discovery of practical production processes for arylsulfur pentafluorides and their higher homologues, bis- and tris(sulfur pentafluorides): Beginning of a new era of “super-trifluoromethyl” arene chemistry and its industry

Scholarly Works

• Yasuo, E.; Aikawa, K.; Nozaki, K.; Okazoe, T. Fluoroalkylated hypervalent sulfur fluorides: radical addition of arylchlorotetrafluoro-λ6-sulfanes to tetrafluoroethylene. Chemical Science 2023, 14, 12379–12385. doi:10.1039/d3sc04837c
• Ritchhart, A.; Chen, Z.; Behera, A.; Jeon, I.-R.; Chapman, K. W.; Vaikuntanathan, S.; Anderson, J. S. Cluster-Spin-Glass Magnetic Behavior and Morphology in the Coordination Polymer Alloys FeyCo1-yBTT. Journal of the American Chemical Society 2023, 145, 24089–24097. doi:10.1021/jacs.3c07527
• Nikul'shin, P. V.; Maksimov, A. M.; Gatilov, Y. V.; Kovtonyuk, V. N.; Bredikhin, R. A. One-pot synthesis of perfluorinated benzenedithiols from perfluoroarenes and thioacetic acid. Mendeleev Communications 2023, 33, 721–722. doi:10.1016/j.mencom.2023.09.041
• Aggarwal, T.; Hada, K.; Murata, Y.; Sumii, Y.; Tanagawa, K.; Niina, K.; Mori, S.; Escorihuela, J.; Shibata, N. Regio- and Z-Selective Alkyne Hydroamination and Hydrophenoxylation using Tetrafluoro-λ6 -Sulfanyl Alkynes under Superbasic, Naked Anion Conditions. Angewandte Chemie (International ed. in English) 2023, 62, e202307090. doi:10.1002/anie.202307090
• Aggarwal, T.; Hada, K.; Murata, Y.; Sumii, Y.; Tanagawa, K.; Niina, K.; Mori, S.; Escorihuela, J.; Shibata, N. Regio‐ and Z‐Selective Alkyne Hydroamination and Hydrophenoxylation using Tetrafluoro‐λ6‐Sulfanyl Alkynes under Superbasic, Naked Anion Conditions. Angewandte Chemie 2023, 135. doi:10.1002/ange.202307090
• Kordnezhadian, R.; Zogu, A.; Borgarelli, C.; Van Lommel, R.; Demaerel, J.; De Borggraeve, W. M.; Ismalaj, E. De-Risking S-F Bond Formation: A Gas Cylinder-Free Strategy to Access S(IV) and S(VI) Fluorinated Compounds. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 29, e202300361. doi:10.1002/chem.202300361
• Mori, S.; Hada, K.; Shibata, N. 直線的分子連結を実現するテトラフルオロスルファニル化合物群:合成と開拓. Journal of Synthetic Organic Chemistry, Japan 2023, 81, 428–438. doi:10.5059/yukigoseikyokaishi.81.428
• Mori, S.; Kagechika, H. Development of Bioactive Molecules Bearing Hexacoordinated Sulfur Fluoride. Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 2023, 143, 429–434. doi:10.1248/yakushi.22-00205-2
• James, R. D.; Alqahtani, L. S.; Mallows, J.; Flint, H. V.; Waddell, P. G.; Woodford, O. J.; Gibson, E. A. Pentafluorosulfanyl-functionalised BODIPY push-pull dyes for p-type dye-sensitized solar cells. Sustainable energy & fuels 2023, 7, 1494–1501. doi:10.1039/d2se00977c
• Mahmoud, E. M.; Iwasaki, H.; Hada, K.; Murata, Y.; Sumii, Y.; Shibata, N. Synthesis of Pyridine-SF4-Alkynes via Light-Promoted Radical Coupling of Pyridine-SF4-Chlorides and EBX Reagents. Bulletin of the Chemical Society of Japan 2023, 96, 110–112. doi:10.1246/bcsj.20220330
• Dudziński, P.; Matsnev, A. V.; Thrasher, J. S.; Haufe, G. Reactions of difluoro-pentafluorosulfanyl-iodomethane (SF5CF2I) with electronically different types of alkenes. Journal of Fluorine Chemistry 2022, 264, 110051. doi:10.1016/j.jfluchem.2022.110051
• Zhao, X.; Shou, J.-Y.; Newton, J. J.; Qing, F.-L. trans-Trifluoromethyltetrafluorosulfanyl Chloride: Selective Synthesis and Reaction with Diazo Compounds. Organic letters 2022, 24, 8412–8416. doi:10.1021/acs.orglett.2c03540
• Eder, T.; Buß, F.; Wilm, L. F. B.; Seidl, M.; Podewitz, M.; Dielmann, F. Oxidative Fluorination of Selenium and Tellurium Compounds using a Thermally Stable Phosphonium SF5− Salt Accessible from SF6. Angewandte Chemie 2022, 134. doi:10.1002/ange.202209067
• Eder, T.; Buß, F.; Wilm, L. F. B.; Seidl, M.; Podewitz, M.; Dielmann, F. Oxidative Fluorination of Selenium and Tellurium Compounds using a Thermally Stable Phosphonium SF5 - Salt Accessible from SF6. Angewandte Chemie (International ed. in English) 2022, 61, e202209067. doi:10.1002/anie.202209067
• Mori, S.; Tsuemoto, N.; Kawachi, E.; Takubo, C.; Tanatani, A.; Kagechika, H. Development of retinoic acid receptor antagonists bearing trans-SF4-alkynyl structure as a linear linker. Tetrahedron 2022, 123, 132967. doi:10.1016/j.tet.2022.132967
• Shou, J.-Y.; Qing, F.-L. Three-Component Reaction of Pentafluorosulfanyl Chloride, Alkenes and Diazo Compounds and Synthesis of Pentafluorosulfanylfurans. Angewandte Chemie (International ed. in English) 2022, 61, e202208860. doi:10.1002/anie.202208860
• Kordnezhadian, R.; Li, B.-Y.; Zogu, A.; Demaerel, J.; De Borggraeve, W. M.; Ismalaj, E. Chemistry of Pentafluorosulfanyl Derivatives and Related Analogs: From Synthesis to Applications. Chemistry (Weinheim an der Bergstrasse, Germany) 2022, 28, e202201491. doi:10.1002/chem.202201491
• Shou, J.; Qing, F. Three‐Component Reaction of Pentafluorosulfanyl Chloride, Alkenes and Diazo Compounds and Synthesis of Pentafluorosulfanylfurans. Angewandte Chemie 2022, 134. doi:10.1002/ange.202208860
• Kraemer, Y.; Bergman, E. N.; Togni, A.; Pitts, C. R. Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride. Angewandte Chemie (International ed. in English) 2022, 61, e202205088. doi:10.1002/anie.202205088
• Kraemer, Y.; Bergman, E. N.; Togni, A.; Pitts, C. R. Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride. Angewandte Chemie 2022, 134. doi:10.1002/ange.202205088

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