Amino-substituted diazocines as pincer-type photochromic switches

Hanno Sell, Christian Näther and Rainer Herges

Beilstein J. Org. Chem. 2013, 9, 1–7. doi:10.3762/bjoc.9.1

Supporting Information

1H NMR spectra of 4 and 5 before and after the irradiation with 405 nm, and 1H NMR binding study of 3,3-acetamido-EBAB (5) with ethylenediamine. cif-Files of X-ray crystal structures of cis-4 and cis-5, and gaussian09 input file of the geometry optimization of the complex of cis-5 and ethylenediamine (DFT B3LYP/6-31+G**).

Supporting Information File 1: Additional NMR spectra and 1H NMR binding study of 3,3-acetamido-EBAB (5) with ethylenediamine.
Format: PDF Size: 662.3 KB Download
Supporting Information File 2: Crystallographic information file of compound cis-4.
Format: CIF Size: 11.8 KB Download
Supporting Information File 3: Crystallographic information file of compound cis-5.
Format: CIF Size: 10.3 KB Download
Supporting Information File 4: Gaussian09 input file of the geometry optimization of the complex of cis-5 and ethylenediamine.
Format: GJF Size: 9.4 KB Download

References

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Molecular switches and cages

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