Molecular switches and cages

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Editor: Prof. Dirk Trauner
Ludwig-Maximilians-Universität München
 
Molecular switches can toggle between two or more stable states encoding different physical features. They allow complex systems to respond to changes in their environment defined by light intensity, pH, temperature or voltage. As such, molecular switches play a key role in biology and information technology and have become important components of advanced materials. Chemists have developed a large number of synthetic switches, complementing the many types found in nature. Given their prominence in biology, it is not surprisingly that photoswitches, which are actuated by ultraviolet, visible or infrared light, have been an especially productive field of study.

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Molecular switches and cages

  • Dirk Trauner

Beilstein J. Org. Chem. 2012, 8, 870–871, doi:10.3762/bjoc.8.97

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Published 13 Jun 2012

The importance of the rotor in hydrazone-based molecular switches

  • Xin Su,
  • Timo Lessing and
  • Ivan Aprahamian

Beilstein J. Org. Chem. 2012, 8, 872–876, doi:10.3762/bjoc.8.98

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Published 13 Jun 2012

meta-Oligoazobiphenyls – synthesis via site-selective Mills reaction and photochemical properties

  • Raphael Reuter and
  • Hermann A. Wegner

Beilstein J. Org. Chem. 2012, 8, 877–883, doi:10.3762/bjoc.8.99

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Published 13 Jun 2012

Intramolecular bridges formed by photoswitchable click amino acids

  • Christian Hoppmann,
  • Ronald Kühne and
  • Michael Beyermann

Beilstein J. Org. Chem. 2012, 8, 884–889, doi:10.3762/bjoc.8.100

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Published 13 Jun 2012

Building photoswitchable 3,4'-AMPB peptides: Probing chemical ligation methods with reducible azobenzene thioesters

  • Gehad Zeyat and
  • Karola Rück-Braun

Beilstein J. Org. Chem. 2012, 8, 890–896, doi:10.3762/bjoc.8.101

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Published 18 Jun 2012

Multistep organic synthesis of modular photosystems

  • Naomi Sakai and
  • Stefan Matile

Beilstein J. Org. Chem. 2012, 8, 897–904, doi:10.3762/bjoc.8.102

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Published 19 Jun 2012

Diarylethene-modified nucleotides for switching optical properties in DNA

  • Sebastian Barrois and
  • Hans-Achim Wagenknecht

Beilstein J. Org. Chem. 2012, 8, 905–914, doi:10.3762/bjoc.8.103

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Published 20 Jun 2012

On the bromination of the dihydroazulene/vinylheptafulvene photo-/thermoswitch

  • Virginia Mazzanti,
  • Martina Cacciarini,
  • Søren L. Broman,
  • Christian R. Parker,
  • Magnus Schau-Magnussen,
  • Andrew D. Bond and
  • Mogens B. Nielsen

Beilstein J. Org. Chem. 2012, 8, 958–966, doi:10.3762/bjoc.8.108

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Published 27 Jun 2012

Synthesis and anion recognition properties of shape-persistent binaphthyl-containing chiral macrocyclic amides

  • Marco Caricato,
  • Nerea Jordana Leza,
  • Claudia Gargiulli,
  • Giuseppe Gattuso,
  • Daniele Dondi and
  • Dario Pasini

Beilstein J. Org. Chem. 2012, 8, 967–976, doi:10.3762/bjoc.8.109

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Published 28 Jun 2012

Toward unidirectional switches: 2-(2-Hydroxyphenyl)pyridine and 2-(2-methoxyphenyl)pyridine derivatives as pH-triggered pivots

  • Christina Tepper and
  • Gebhard Haberhauer

Beilstein J. Org. Chem. 2012, 8, 977–985, doi:10.3762/bjoc.8.110

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Published 29 Jun 2012

Recent advances towards azobenzene-based light-driven real-time information-transmitting materials

  • Jaume García-Amorós and
  • Dolores Velasco

Beilstein J. Org. Chem. 2012, 8, 1003–1017, doi:10.3762/bjoc.8.113

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Published 04 Jul 2012

The effect of the formyl group position upon asymmetric isomeric diarylethenes bearing a naphthalene moiety

  • Renjie Wang,
  • Shouzhi Pu,
  • Gang Liu and
  • Shiqiang Cui

Beilstein J. Org. Chem. 2012, 8, 1018–1026, doi:10.3762/bjoc.8.114

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Published 05 Jul 2012

Control over molecular motion using the cistrans photoisomerization of the azo group

  • Estíbaliz Merino and
  • María Ribagorda

Beilstein J. Org. Chem. 2012, 8, 1071–1090, doi:10.3762/bjoc.8.119

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Published 12 Jul 2012

Design and synthesis of a photoswitchable guanidine catalyst

  • Philipp Viehmann and
  • Stefan Hecht

Beilstein J. Org. Chem. 2012, 8, 1825–1830, doi:10.3762/bjoc.8.209

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Published 24 Oct 2012

Design and synthesis of quasi-diastereomeric molecules with unchanging central, regenerating axial and switchable helical chirality via cleavage and formation of Ni(II)–O and Ni(II)–N coordination bonds

  • Vadim A. Soloshonok,
  • José Luis Aceña,
  • Hisanori Ueki and
  • Jianlin Han

Beilstein J. Org. Chem. 2012, 8, 1920–1928, doi:10.3762/bjoc.8.223

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Published 13 Nov 2012

A bisazobenzene crosslinker that isomerizes with visible light

  • Subhas Samanta,
  • Harris I. Qureshi and
  • G. Andrew Woolley

Beilstein J. Org. Chem. 2012, 8, 2184–2190, doi:10.3762/bjoc.8.246

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Published 14 Dec 2012

Amino-substituted diazocines as pincer-type photochromic switches

  • Hanno Sell,
  • Christian Näther and
  • Rainer Herges

Beilstein J. Org. Chem. 2013, 9, 1–7, doi:10.3762/bjoc.9.1

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Published 02 Jan 2013

A chemist and biologist talk to each other about caged neurotransmitters

  • Graham C.R. Ellis-Davies

Beilstein J. Org. Chem. 2013, 9, 64–73, doi:10.3762/bjoc.9.8

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Published 11 Jan 2013

Synthesis and testing of the first azobenzene mannobioside as photoswitchable ligand for the bacterial lectin FimH

  • Vijayanand Chandrasekaran,
  • Katharina Kolbe,
  • Femke Beiroth and
  • Thisbe K. Lindhorst

Beilstein J. Org. Chem. 2013, 9, 223–233, doi:10.3762/bjoc.9.26

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Published 01 Feb 2013

Spin state switching in iron coordination compounds

  • Philipp Gütlich,
  • Ana B. Gaspar and
  • Yann Garcia

Beilstein J. Org. Chem. 2013, 9, 342–391, doi:10.3762/bjoc.9.39

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Published 15 Feb 2013
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