Spin state switching in iron coordination compounds

Philipp Gütlich, Ana B. Gaspar and Yann Garcia
Beilstein J. Org. Chem. 2013, 9, 342–391. https://doi.org/10.3762/bjoc.9.39

Cite the Following Article

Spin state switching in iron coordination compounds
Philipp Gütlich, Ana B. Gaspar and Yann Garcia
Beilstein J. Org. Chem. 2013, 9, 342–391. https://doi.org/10.3762/bjoc.9.39

How to Cite

Gütlich, P.; Gaspar, A. B.; Garcia, Y. Beilstein J. Org. Chem. 2013, 9, 342–391. doi:10.3762/bjoc.9.39

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Wang, M.; Robeyns, K.; Rotaru, A.; Hochdörffer, T.; Wolff, M.; Maskowicz, D.; Wolny, J. A.; Schuenemann, V.; Sawczak, M.; Jendrzejewski, R.; Garcia, Y. Structure–Property Relations in Aryl-Functionalized [Fe(H2Bpz2)2(bipy-R)] Spin Crossover Complexes. Inorganic Chemistry 2026. doi:10.1021/acs.inorgchem.6c02842
  • Dey, B.; Arumugam, R.; Cirera, J.; Ferreira, L. P.; Martinho, P. N.; Chandrasekhar, V. Carbazole-functionalized Fe(III) spin-crossover complexes exhibiting fluorescence quenching. Dalton transactions (Cambridge, England : 2003) 2026, 55, 12484–12494. doi:10.1039/d6dt00705h
  • Ay, B.; Ishida, T. A new [Fe(L)2(NCS)2] complex with Δ- and Λ-type molecular sites exhibiting incomplete spin crossover. Inorganic Chemistry Communications 2026, 191, 117186. doi:10.1016/j.inoche.2026.117186
  • Takahashi, K.; Kasazaki, T.; Tsuchiya, S.; Ueda, K.; Miyawaki, A.; Murata, S.; Sakurai, T.; Ohta, H.; Osakai, T. 2,2′-Azobisphenolate Ligand Bearing Electron-Donating Methoxy Substituents: Spin-Crossover Ligand Field for a Fe(III) Complex and Stabilization of Ligand-Centered Oxidation Species Due to Its Resonance Effect. Inorganics 2026, 14, 223. doi:10.3390/inorganics14090223
  • St Michel, R. G.; Jang, R. J.; Garrison, A. G.; Kevlishvili, I.; Kulik, H. J. The BOS-Lig Data Set: Accurate Ligand Charges from a Consensus Approach for 66,810 Experimentally Synthesized Ligands. Journal of chemical information and modeling 2026, 66, 8336–8348. doi:10.1021/acs.jcim.6c01063
  • Sarkar, D.; Halder, P.; Mondal, P. K.; Hossain, S. M.; Li, Y.; Pechousek, J.; Mondal, A. Controlling Spin States in Metallosupramolecular Iron(II) Grid Architectures through Light, Temperature, and Protonation. Inorganic chemistry 2026, 65, 15746–15758. doi:10.1021/acs.inorgchem.6c01858
  • Huang, L.; Djukic, J.-P. Spin-crossover in metal complex-promoted homogenous catalysis. Frontiers in chemistry 2026, 14, 1854732. doi:10.3389/fchem.2026.1854732
  • Liu, J.; Dobrzycki, Ł.; Talham, D. R. Spin Crossover Heterostructures for Inducing Strain: Two Contrasting Responses in MoS2 Nanosheets. ACS applied materials & interfaces 2026, 18, 35643–35653. doi:10.1021/acsami.6c06097
  • Li, W.; Xia, S.; Liu, J.; Bi, Y.; Li, X.; Garcia, Y. FeII based spin crossover Hofmann-type MOFs: Recent progress in spin state regulation, multifunctionality and applications. Coordination Chemistry Reviews 2026, 566, 218195. doi:10.1016/j.ccr.2026.218195
  • Li, X.; Wong, J. W. L.; Wang, M.; Draoui, Y.; Wolff, M.; Robeyns, K.; Rotaru, A.; Garcia, Y. Crystal engineering of p -sulfocinnamic acid into mononuclear cationic Fe( ii ), Co( ii ) and Fe( iii ) complexes. CrystEngComm 2026, 28, 3449–3457. doi:10.1039/d6ce00068a
  • Keivanshekooh, H.; Safaei, E.; Wojtczak, A.; Kozlevčar, B.; Jagličić, Z. Thermo-switching spin crossover in iron(III) complexes of Bis(phenol)diamine ligands. Journal of Molecular Structure 2026, 1363, 145687. doi:10.1016/j.molstruc.2026.145687
  • Šuligoj, A.; Maver, K.; Arčon, I.; Dražić, G.; Zabukovec Logar, N.; Pintar, A.; Novak Tušar, N. Light‐Induced Structural Reorganization of Fe Centers Unlocks High Efficiency of Visible‐Light Photo‐Fenton Water Cleaning Catalyst. ENERGY & ENVIRONMENTAL MATERIALS 2026. doi:10.1002/eem2.70400
  • Schöbinger, M.; Huber, M.; Mundigler, S.; Stöger, B.; Reissner, M.; Weinberger, P. Spin-crossover tuning in synergistic luminescent Fe( ii ) coordination compounds via topochemical [4 + 4] photocycloaddition of an anthracene-based ligand. Inorganic Chemistry Frontiers 2026, 13, 4638–4651. doi:10.1039/d5qi01281c
  • Turanova, O. A.; Turanov, A. N. Spin crossover Fe(III) complexes with tetradentate Schiff base ligands. Reviews in Inorganic Chemistry 2026. doi:10.1515/revic-2026-0022
  • Badala Viswanatha, C.; Stöckl, J.; Arnoldi, B.; Knippertz, J.; Haag, F.; Paulsen, H.; Wolny, J. A.; Aeschlimann, M.; Schünemann, V.; Stadtmüller, B. Impact of Cooperativity on the Spatial and Temporal Evolution of the Light-Induced Spin-State Switching of the Fe(phen) 2 (SCN) 2 Spin-Crossover Complex. The Journal of Physical Chemistry C 2026, 130, 7231–7241. doi:10.1021/acs.jpcc.6c01676
  • Pacheco, M.; Jesuman, A.; Maqueda-Márquez, H.; González-Platas, J.; Gaspar, A. B. "Ammonia Induced Framework Transformations and Spin-Crossover in Fe(II) Hofmann MOFs". Inorganic chemistry 2026, 65, 8052–8060. doi:10.1021/acs.inorgchem.6c00626
  • Pacheco, M.; Maqueda-Márquez, H.; Jesuman, A.; Gaspar, A. B. Reversible I2 Uptake Induces Record-High Spin-Crossover Hysteresis in a Fe(II) Hofmann-Type MOF. Chemistry (Weinheim an der Bergstrasse, Germany) 2026, 32, e70935. doi:10.1002/chem.70935
  • Harding, P.; Harding, D. J. A beginner's guide to spin crossover. CrystEngComm 2026, 28, 1707–1726. doi:10.1039/d6ce00107f
  • Zhang, X.-Y.; Shao, Z.; Zhang, M.-Y.; Chen, D.-Y.; Liu, Q.; Zhang, C.-C.; Meng, Y.-S.; Liu, T.; Wang, X.-Y. Unveiling the role of counter-anions in symmetry breaking and spin crossover in mononuclear FeIII complexes. Science China Chemistry 2026, 69, 3403–3411. doi:10.1007/s11426-025-3169-y
  • Wang, M.; Draoui, Y.; Robeyns, K.; Yadav, J.; Han, Z.; Wolff, M.; Maskowicz, D.; Rotaru, A.; Pinkowicz, D.; Sawczak, M.; Jendrzejewski, R.; Garcia, Y. Fe(II) Complexes Incorporating Anthracene-2-sulfonate Anion: Unraveling Photodimerization Potential and Spin Crossover Behavior. Crystal Growth & Design 2026, 26, 2981–2990. doi:10.1021/acs.cgd.5c01701

Patents

  • MARQUES MOROS FRANCISCO; CANET FERRER JOSÉ; CORONADO MIRALLES EUGENIO; GAVARA EDO MIGUEL JOSÉ. USE OF THE COMPOUND [IRON (II) (HYDROTRIS (3,5-DIMETHYL-1-PYRAZOLYL) BORATE)2] AS A TEMPERATURE SENSOR (Machine-translation by Google Translate, not legally binding). ES 2995408 A1, Feb 10, 2025.
  • MARQUÉS MOROS FRANCISCO; CANET FERRER JOSÉ; CORONADO MIRALLES EUGENIO; GAVARA EDO MIGUEL JOSÉ. USE OF THE COMPOUND [IRON(II) (HYDROTRIS(3,5-DIMETHYL-1-PYRAZOLYL)BORATE)2] AS A TEMPERATURE SENSOR. WO 2025027225 A1, Feb 6, 2025.
  • RENZ FRANZ; SINDELAR RALF. Geträgerte molekulare Schalter. DE 102014107644 A1, July 16, 2015.
Other Beilstein-Institut Open Science Activities