3 article(s) from Amii, Hideki
Phthalide and fluorinated phthalides (1).
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Plausible reaction mechanism for the formation of phthalide 1a.
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Synthesis of fluorinated phthalides 1.
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Asymmetric synthesis of 1a using a chiral auxiliary.
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Catalytic asymmetric synthesis of 1a.
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Beilstein J. Org. Chem. 2018, 14, 182–186, doi:10.3762/bjoc.14.12
Trifluoromethylation using trifluoroacetate.
Decarboxylative pentafluoroethylation and its application.
Trifluoromethyation with trifluoroacetate in a flow system.
Trifluoromethylation of 4-bromotoluene by [(NHC)Cu(TFA)].
Trifluoromethylation of aryl iodides with small amounts of Cu and Ag2O. aThe yield was determined b...
C–H trifluoromethylation of arenes using trifluoroacetic acid.
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CF3Cu generated from chlorofluoroacetate and CuI.
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[18F]Trifluoromethyation with difluorocarbenes for PET. aRadiochemical yield determined by HPLC.
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Trifluoromethylation with trifluoroacetate and copper iodide.
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Preparation of trifluoromethylcopper from trifluoromethyl ketone.
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Trifluoromethylation of aryl iodides. aIsolated yield. b1 equivalent each of CF3Cu reagent and 1,10...
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Pentafluoroethylation of aryl bromides. aYield was determined by 19F NMR analysis using benzotriflu...
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Perfluoroalkylation reactions of arylboronic acids. aIsolated yield. bDMF was used instead of tolue...
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Trifluoromethylation with silylated hemiaminal of fluoral.
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Catalytic trifluoromethylation with a fluoral derivative.
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The scope of Cu-catalyzed aromatic trifluoromethylation. The yield was determined by 19F NMR analys...
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Plausible mechanism of Cu-catalyzed aromatic trifluoromethylation .
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Beilstein J. Org. Chem. 2015, 11, 2661–2670, doi:10.3762/bjoc.11.286
Direct fluorination using microreactor systems.
Use of DAST in continuous-flow reactors.
Flow microreactor synthesis of fluorinated epoxides.
Highly controlled isomerization of gem-difluoroalkenes.
Flow system for catalytic aromatic fluorination.
Continuous-flow reactor for electrophilic aromatic fluorination.
Examples of [18F]-radiolabeled molecular imaging probes.
Flow microreactor synthesis of dipeptides.
Flow synthesis involving SNAr reactions.
Flow synthesis of fluoroquinolone antibiotics.
Highly controlled formation of PFPMgBr.
Selective flow synthesis of photochromic diarylethenes.
Flow microreactor system for perfluoroalkylation by generation of perfluoroalkyllithiums in the pre...
Integrated flow microreactor system for perfluoroalkylation by generation of perfluoroalkyllithiums...
Beilstein J. Org. Chem. 2013, 9, 2793–2802, doi:10.3762/bjoc.9.314
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