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1 article(s) from Belyanskaya, Diana S

Reactions of N,3-diarylpropiolamides with arenes under superelectrophilic activation: synthesis of 4,4-diaryl-3,4-dihydroquinolin-2(1H)-ones and their derivatives

Larisa Yu. Gurskaya,
Diana S. Belyanskaya,
Dmitry S. Ryabukhin,
Denis I. Nilov,
Irina A. Boyarskaya and
Aleksander V. Vasilyev

Full Research Paper
Published 11 May 2016

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1. Graphical Abstract
2. Scheme 1: Transformations of 3-aryl-N-(aryl)propiolamides 1 into 4-arylquinolin-2(1H)-ones 3 or 4,4-diaryl-3,...
  
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3. Figure 1: Molecular structure of 2f (ellipsoid contours of probability levels are 50%).
  
  Jump to Figure 1
4. Scheme 2: N-Formylation and N-acylation of dihydroquinolinones 2.
  
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5. Scheme 3: Superelectrophilic activation of the N-formyl group of compounds 5 and their reaction with benzene.
  
  Jump to Scheme 3
6. Figure 2: LUMO of species C1 and D1.
  
  Jump to Figure 2
Supp. Info

Beilstein J. Org. Chem. 2016, 12, 950–956, doi:10.3762/bjoc.12.93

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