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Beilstein J. Org. Chem. 2026, 22, 620–627, doi:10.3762/bjoc.22.48
Graphical Abstract
Figure 1: NHC–Cu complexes investigated in this study.
Scheme 1: Hypothetical mechanism for FA decomposition via decarboxylation of NHC–Cu–formato species.
Figure 2: Decomposition of FA catalyzed by NHC–Cu complexes in the presence of PhSiH3. Reaction conditions: f...
Figure 3: Decomposition of FA catalyzed by NHC–Cu complexes in the presence of different silanes. Reaction co...
Scheme 2: Isotopic labeling experiments.
Scheme 3: Proposed catalytic cycle for the NHC–Cu-catalyzed FA dehydrogenation.
Scheme 4: Dehydrogenative coupling of phenylsilane.
Beilstein J. Org. Chem. 2020, 16, 482–491, doi:10.3762/bjoc.16.43
Scheme 1: Formation of sulfonyltriazoles and sulfonamidines.
Figure 1: Catalytic systems used in this study.
Scheme 2: Synthetic access to complexes 4–6 [30].
Scheme 3: Variation of sulfonylazides. Reaction conditions: phenylacetylene (0.5 mmol), sulfonyl azide (0.6 m...
Scheme 4: Variation of alkynes. Reaction conditions: alkyne (0.5 mmol), tosyl azide (0.6 mmol), diisopropylam...
Scheme 5: Variation of the amine substrate. Reaction conditions: phenylacetylene (0.5 mmol), tosyl azide (0.6...
Scheme 6: Reactivity of “non-sulfonyl” azide [33]. Reaction conditions: phenylacetylene (0.5 mmol), benzyl azide ...
Scheme 7: Reactivity of diphenylphosphoryl azide. Reaction conditions: phenylacetylene (0.5 mmol), diphenylph...
Scheme 8: Proposed mechanism for the formation of sulfonamidine.
Scheme 9: Stoichiometric reaction between 6 and 8.
Scheme 10: Synthesis of copper-acetylide intermediate A via [Cu(Cl)(Triaz)].
Scheme 11: Catalytic reaction involving copper-acetylide complex A.
Beilstein J. Org. Chem. 2015, 11, 1520–1527, doi:10.3762/bjoc.11.166
Figure 1: Examples of ruthenium complexes used in olefin metathesis reactions.
Scheme 1: Synthesis of the mixed phosphine/phosphite complex 1.
Figure 2: Molecular structure of mixed phosphine/phosphite complex 1. Hydrogen atoms are omitted for clarity.
Scheme 2: Synthesis of the bis-phosphite complex 2.
Figure 3: Molecular structure of 2 and the ylide 3. Hydrogen atoms and solvent molecules are omitted for clar...
Figure 4: Reaction profiles of mixed phosphine/phosphite 1 and phosphine-based Ind-I in the RCM of 4 (lines a...