2 article(s) from Champagne, Pier Alexandre
- Full Research Paper
- Published 09 Jan 2018
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Graphical Abstract
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Figure 1: C–F activation of benzylic fluorides to generate benzylamine or diarylmethane products.
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Figure 2: 7-[2H1]-(R)-Benzyl fluoride ((R)-1).
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Scheme 1: Synthesis of enantioenriched 7-[2H1]-(R)-benzyl fluoride ((R)-1) from benzaldehyde (2).
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Figure 3: Partial 2H{1H} NMR (107.5 MHz) with PBLG in CHCl3 (13% w/w). (A) racemic sample of 6 (from Table 1, entry ...
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Scheme 2: Synthesis of enantioenriched (S)-diarylmethane 10 from diaryl ketone 11 and confirmation of configu...
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Figure 4: Possible reactive intermediates for C–F activation of benzyl fluoride 1 with strong hydrogen bond d...
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- Letter
- Published 13 Nov 2013
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Figure 1: SN2 reaction of activated alkyl fluorides and calculated transition state for the reaction of morph...
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Figure 2: Proposed activation of C–F bonds mediated by a triol.
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