2 article(s) from Dorovatovskii, Pavel V
- Full Research Paper
- Published 16 Aug 2018
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Scheme 1: Difunctionalization of double C=C bond with the formation of C–O and C–I bonds.
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Scheme 2: Iodo-oxyimidation of styrenes 1a–k with preparation of products 3aa–ka, 3ab–db, 3fb, 3hb, and 3kb.
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Figure 1: Scope of the iodo-oxyimidation of vinylarenes with I2/PhI(OAc)2 system. Reaction conditions: vinyla...
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Figure 2: Molecular structure of 3ca. Atoms are presented as anisotropic displacement parameters (ADP) ellips...
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Scheme 3: The proposed mechanism of iodo-oxyimidation of styrene (1a) using the NHPI/I2/PhI(OAc)2 system with...
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Figure 3: CV curves of styrene (1a, purple), NHPI (2a, red), I2 (blue) and PhI(OAc)2 (green) in 0.1 M n-Bu4NBF...
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Scheme 4: Gram-scale synthesis of compound 3aa.
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Scheme 5: Synthetic utility of the iodo-oxyimides 3aa and 3ab.
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- Full Research Paper
- Published 31 Jul 2018
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Scheme 1: The general structure of triazolylcalix[4]arene derivatives.
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Scheme 2: Synthesis of di- (4a,b) and tetraazido (8a,b) calix[4]arene derivatives. Conditions: Ia: AlkBr, K2CO...
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Figure 1: Molecular structure of 8a (50% ellipsoids). The dashed line indicates the alternative position of t...
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Scheme 3: Synthesis of polyammonium macrocycles 10a,b and 12a,b.
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Figure 2: 2D NOESY H1-H1 NMR spectra of 10b in DMSO-d6.
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Figure 3: The optical response (OR) of the calixarene/EY systems toward adenosine phosphates. Concentration (...
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Figure 4: Supramolecular binding motif of diphosphate (a) and triphosphate (b) groups of nucleotides with the...
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Figure 5: UV spectra of EY (1), 10b–EY (2), and 10b–EY in the presence of 0.005 (3), 0.05 (4), 0.5 (5) and 2 ...
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Scheme 4: Structure of AEPDA and the corresponding AEPCDA–10b polydiacetylene vesicle.
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Figure 6: UV spectra of the AEPCDA polydiacetylene vesicles in the presence of different amounts of 10b; conc...
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Figure 7: Photographs of a portion of a 96-well plate containing AEPCDA–10b polydiacetylene vesicles in the a...
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