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Beilstein J. Org. Chem. 2025, 21, 877–883, doi:10.3762/bjoc.21.71
Graphical Abstract
Scheme 1: Chemodivergent reactivity observed in copper-catalyzed borylative couplings of allylic gem-dichlori...
Scheme 2: Cu-Bpin-mediated dimerization of 4,4-dichoro-2-butenoic acid derivatives.
Scheme 3: Control experiments.
Scheme 4: Proposed mechanism for the Cu-catalyzed dimerization of 4,4-dichoro-2-butenoic acid derivatives.
Scheme 5: a) KOt-Bu-mediated intramolecular cyclization of 9. b) Direct formation of cyclopropane 20 from gem...
Beilstein J. Org. Chem. 2020, 16, 611–615, doi:10.3762/bjoc.16.56
Scheme 1: Synthesis of mixed alkyl alkenyl phosphonates.
Scheme 2: Scope of the copper-catalyzed alkenylation of dialkyl phosphonates. Reactions run on a 0.2 mmol sca...