Author

1 article(s) from Gorbunova, Yelizaveta

AlBr₃-Promoted stereoselective anti-hydroarylation of the acetylene bond in 3-arylpropynenitriles by electron-rich arenes: synthesis of 3,3-diarylpropenenitriles

Yelizaveta Gorbunova,
Dmitry S. Ryabukhin and
Aleksander V. Vasilyev

Full Research Paper
Published 01 Nov 2021

PDF
Album
1. Graphical Abstract
2. Scheme 1: AlBr₃-promoted hydroarylation of the acetylene bond of 3-arylpropynenitriles 1a–c by arenes with th...
  
  Jump to Scheme 1
3. Scheme 2: Plausible mechanism for reaction of acetylene nitriles 1 with arenes leading to nitriles 2.
  
  Jump to Scheme 2
4. Scheme 3: Cyclization of nitriles 2c,g into indanones 3a,b in TfOH.
  
  Jump to Scheme 3
5. Scheme 4: Hydrophenylation of nitriles 1a,b by benzene in TfOH leading to nitriles 2a,b.
  
  Jump to Scheme 4
Supp. Info

Graphical Abstract

Beilstein J. Org. Chem. 2021, 17, 2663–2667, doi:10.3762/bjoc.17.180

Full Text

Other Beilstein-Institut Open Science Activities

Keep Informed

RSS Feed

Subscribe to our Latest Articles RSS Feed.

Subscribe

Email Notification

Register and get informed about new articles.

Register

Follow the Beilstein-Institut

Twitter: @BeilsteinInst