1 article(s) from Hargitai, Csilla
Rearrangement of methylenedioxy-substituted aminoaldehyde 1a to regioisomer 2a and formation of the...
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Synthesis of 1-arylisoindoles 6 and formation of dimers 5.
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Rearrangement of aminoaldehydes 1 to regioisomers 2 and formation of dimer-like products 3 and 8.
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X-ray structures of compounds 3b (left) and 8b (right).
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Proposed mechanism of the isomerization of aldehydes 1 via isoindoles 4.
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Proposed mechanism of the formation of dimer-like products 3a,b.
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Proposed mechanism for the formation of dimer-like products 8a,b.
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Dimerization of indole under acidic conditions.
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Gibbs free energy diagram for the 1→2 rearrangement.
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Reaction of o-(pivaloylaminomethyl)benzaldehyde (1e) to give dimer-like products 23a and 23b.
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X-ray structures of compounds 23a (left) and 23b (right).
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Structures of the minimal energy conformer of stereoisomer 23a and those of two minimal energy conf...
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Beilstein J. Org. Chem. 2020, 16, 1636–1648, doi:10.3762/bjoc.16.136
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