3 article(s) from Itami, Kenichiro
C–H functionalization of HBCs. (a) Perchlorinated HBC. (b) Borylated HBC substituted by 2,4,6-trime...
Jump to Figure 1
Synthesis of hexaborylated HBC 1. (a) Solvent screening of six-fold C–H borylation of unsubstituted...
Jump to Figure 2
The structure of 1 confirmed by X-ray crystallographic analysis. (a) ORTEP drawing of 1 with therma...
Jump to Figure 3
Photophysical properties of 1. (a) UV–vis absorption (solid lines) spectra, fluorescence (dotted li...
Jump to Figure 4
Beilstein J. Org. Chem. 2020, 16, 391–397, doi:10.3762/bjoc.16.37
Triaryl-2-pyridylidene (PyC) and PyC-gold(I) complex (AuCl(PyC)).
Yield–time profiles of 4-(4-bromophenyl)-5-methylisoxazole (3ba) and methyl 2-iodobenzoate (5) with...
Plausible reaction mechanism of gold-catalyzed oxidative C–H arylation of heteroarenes with arylsil...
Jump to Scheme 1
ORTEP drawing of AuCl3(PyC) with 50% probability. Hydrogen atoms and solvent are omitted for clarit...
Direct observation and isolation of carbene-gold(III) complex. Mes = 2,4,6-Me3C6H2, Xyl = 2,6-Me2C6H...
Jump to Scheme 2
Beilstein J. Org. Chem. 2015, 11, 2737–2746, doi:10.3762/bjoc.11.295
Electrochemical generation of carbocations by oxidative C-C bond dissociation.
Electrochemical generation and accumulation of organosilicon cation by oxidative Si-Si bond dissoci...
Oxidation potentials (Ed; decomposition potential) of disilanes determined by rotating disk electro...
Optimized structures of radical cations of 1,2-diphenyldisilane and 1,2-bis [o-(2-pyridyl)- phenyl]...
Electrochemical generation of organosilicon cation 3d.
Jump to Scheme 3
CSI-MS of organosilicon cation 3d at 0°C.
Optimized structures of organosilicon cation 3d and silyl radical 4d by DFT calculations (B3LYP/LAN...
Reaction of organosilicon cation 3d with p-tolylmagnesium bromide.
Jump to Scheme 4
Beilstein J. Org. Chem. 2007, 3, No. 7, doi:10.1186/1860-5397-3-7
Subscribe to our Latest Articles RSS Feed.
Register and get informed about new articles.
Follow the Beilstein-Institut