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Beilstein J. Org. Chem. 2025, 21, 2739–2754, doi:10.3762/bjoc.21.211
Graphical Abstract
Scheme 1: Current synthetic approaches to aliphatic nitro-NNO-azoxy compounds and the summary of the present ...
Scheme 2: Scope of the discovered electrochemical nitro-NNO-azoxylation of nitrosoalkanes containing electron...
Scheme 3: Synthetic utility and derivatization of synthesized coupling product 2f.
Figure 1: CV-curves of 0.01 M solutions of a) 1a (blue), b) 1f (azure), c) 1c (pink), d) 1i (yellow), e) S4 (...
Figure 2: CV-curves of 0.01 M solutions of a) 1a (blue), b) ADN (red), c) the mixture of 1a and ADN (green), ...
Scheme 4: Control experiments.
Figure 3: Free energy diagram of possible interaction pathways between 1a and dinitramide-derived radical A a...
Scheme 5: Proposed mechanism for electrochemical nitro-NNO-azoxylation of 1-nitro-1-nitroso compounds 1. Free...
Figure 4: Assessment of the NO release from compounds 2a–i, 3f, and 4f.