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Beilstein J. Org. Chem. 2019, 15, 44–51, doi:10.3762/bjoc.15.4
Graphical Abstract
Scheme 1: Strategy for sequential ROMP of 1 to yield 3.
Scheme 2: ROMP of 4 and 5 in THF at 0 °C in the presence of 10 mol % of 6.
Scheme 3: Retrosynthesis of 8 from 9.
Scheme 4: Synthesis of monomer 9.
Scheme 5: Synthesis of 14 and 8 by selective olefin metathesis.
Scheme 6: Cyclopolymerization of 15 with a flexible linker.
Scheme 7: Methanolysis of unsymmetrical ladderphane 8.