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Beilstein J. Org. Chem. 2010, 6, No. 65, doi:10.3762/bjoc.6.65
Preparation of the first electrophilic trifluoromethylating reagent and its reaction with a thiophe...
Synthetic routes to S-CF3 and Se-CF3 dibenzochalcogenium salts.
Synthesis of (trifluoromethyl)dibenzotellurophenium salts.
Nitration of (trifluoromethyl)dibenzochalcogenium salts.
Synthesis of a sulphonium salt with a bridged oxygen.
Reactivity of (trifluoromethyl)dibenzochalcogenium salts.
Pd(II)-Catalyzed ortho-trifluoromethylation of heterocycle-substituted arenes by Umemoto’s reagents....
Mild electrophilic trifluoromethylation of β-ketoesters and silyl enol ethers.
Enantioselective electrophilic trifluoromethylation of β-ketoesters.
Preparation of water-soluble S-(trifluoromethyl)dibenzothiophenium salts.
Method for large-scale preparation of S-(trifluoromethyl)dibenzothiophenium salts.
Triflic acid catalyzed synthesis of 5-(trifluoromethyl)thiophenium salts.
Trifluoromethylation of β-ketoesters and dicyanoalkylidenes by S-(trifluoromethyl)benzothiophenium ...
Synthesis of chiral S-(trifluoromethyl)benzothiophenium salt 18 and attempt of enantioselective tri...
Synthesis of O-(trifluoromethyl)dibenzofuranium salts.
Photochemical O- and N-trifluoromethylation by 20b.
Thermal O-trifluoromethylation of phenol by diazonium salt 19a. Effect of the counteranion.
Thermal O- and N-trifluoromethylations.
Method of preparation of S-(trifluoromethyl)diphenylsulfonium triflates.
Reactivity of some S-(trifluoromethyl)diarylsulfonium triflates.
One-pot synthesis of S-(trifluoromethyl)diarylsulfonium triflates.
One-pot synthesis of Umemoto’s type reagents.
Preparation of sulfonium salts by transformation of CF3− into CF3+.
Selected reactions with the new Yagupolskii reagents.
Synthesis of heteroaryl-substituted sulfonium salts.
First neutral S-CF3 reagents.
Synthesis of Togni reagents. aYield for the two-step procedure.
Trifluoromethylation of C-nucleophiles with 37.
Selected examples of trifluoromethylation of S-nucleophiles with 37.
Selected examples of trifluoromethylation of P-nucleophiles with 35 and 37.
Trifluoromethylation of 2,4,6-trimethylphenol with 35.
Examples of O-trifluoromethylation of alcohols with 35 in the presence of 1 equiv of Zn(NTf2)2.
Formation of trifluoromethyl sulfonates from sulfonic acids and 35.
Organocatalytic α-trifluoromethylation of aldehydes with 37.
Synthesis of reagent 42 and mechanism of trifluoromethylation.
Trifluoromethylation of β-ketoesters and dicyanoalkylidenes with 42.