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1 article(s) from Matsuno, Hidetoshi

Electrochemical Friedel–Crafts-type amidomethylation of arenes by a novel electrochemical oxidation system using a quasi-divided cell and trialkylammonium tetrafluoroborate

Hisanori Senboku,
Mizuki Hayama and
Hidetoshi Matsuno

Letter
Published 18 Aug 2022

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1. Graphical Abstract
2. Scheme 1: Generation of N-acyliminium ion: previous and present works.
  
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3. Scheme 2: Electrochemical amidomethylation of indoles 4 in DMA.
  
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4. Scheme 3: Electrochemical amidomethylation of 3-methyl-1H-indole (7) in DMA.
  
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5. Scheme 4: Electrochemical amidomethylation of N-methyl-1H-indole (4a) in DMF.
  
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6. Scheme 5: Probable reaction pathway of the electrochemical amidomethylation.
  
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Graphical Abstract

Beilstein J. Org. Chem. 2022, 18, 1040–1046, doi:10.3762/bjoc.18.105

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