2 article(s) from Minnaard, Adriaan J
- Full Research Paper
- Published 02 Apr 2014
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: Originally proposed structures A and B and revised structures 1 and 2 of putative sex pheromone com...
-
![]()
Scheme 1: Application of the iterative conjugate addition protocol for the preparation of 8.
-
![]()
Scheme 2: Deoxygenation and desilylation of 8.
-
![]()
Scheme 3: Vinylogous Horner–Wadsworth–Emmons olefination.
-
![]()
Scheme 4: Synthesis of α,β-unsaturated ester 15 using a Wittig reaction.
-
![]()
Scheme 5: Completion of the synthesis of the putative sex pheromone 2.
-
-
Supp. Info
- Letter
- Published 06 Nov 2013
-
PDF -
Album-
![]()
Graphical Abstract
-
![]()
Figure 1: (S)-1,3-dihydroxy-3,7-dimethyl-6-octen-2-one (1).
-
![]()
Scheme 1: Selective oxidation of glycerol [15] and methyl α-D-glucopyranoside.
-
![]()
Scheme 2: Approach of synthesis of (S)-1.
-
![]()
Scheme 3: Synthesis of (S)-1 from geraniol. Reagents and conditions: a) D-(−)-diisopropyl tartrate, Ti(OiPr)4...
-
![]()
Scheme 4: Synthesis starting from nerol. Reagents and conditions: a) L-(+)-diisopropyl tartrate, Ti(OiPr)4, t...
-
-
Supp. Info
