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Beilstein J. Org. Chem. 2026, 22, 662–671, doi:10.3762/bjoc.22.50
Graphical Abstract
Scheme 1: Selected photocatalytic trifluoromethylation procedures.
Scheme 2: Scope of the trifluoromethylation. Summary yield for all formed isomers is shown for each product. ...
Scheme 3: Radical trapping reactions.
Scheme 4: Proposed mechanism.
Scheme 5: Addition of CF3 radical to benzene and TMB.
Beilstein J. Org. Chem. 2025, 21, 1480–1488, doi:10.3762/bjoc.21.110
Scheme 1: Background and conception.
Scheme 2: Reaction scope of iodonium salts 1 and isonitriles. aReaction conditions: isonitrile (0.2 mmol), io...
Scheme 3: Selectivity experiments and scope of unsymmetrical iodoniums salts. aReaction conditions: 2-isocyan...
Scheme 4: Proposed reaction mechanism.
Beilstein J. Org. Chem. 2020, 16, 1305–1312, doi:10.3762/bjoc.16.111
Scheme 1: A) Properties and B) synthesis of CF3O-bearing arenes; C) trifluoromethoxylation using the “second”...
Scheme 2: Optimization of residence time. 19F NMR yields are reported.
Scheme 3: Scope of photoredox trifluoromethoxylation in continuous-flow. In case of different products, the m...
Figure 1: Effect of KH2PO4 – other substrates. a Conditions as for entry 15 (Table 2), 1 h residence time; b conditi...