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1 article(s) from Richardson, Mark B

A practical synthesis of long-chain iso-fatty acids (iso-C₁₂–C₁₉) and related natural products

Mark B. Richardson and
Spencer J. Williams

Beilstein J. Org. Chem. 2013, 9, 1807–1812, doi:10.3762/bjoc.9.210

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Figure 1: Structures of iso-fatty acids.

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Scheme 1: Synthesis of iso-C₁₂ 1, iso-C₁₃ 2, and iso-C₁₄ 3 fatty acids from methyl undecylenate (9). Reagents...

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Scheme 2: Synthesis of iso-C₁₅ 4, iso-C₁₆ 5, and iso-C₁₇ 6 fatty acids from pentadecanolide (15). Reagents an...

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Scheme 3: Synthesis of iso-C₁₈ 7 and iso-C₁₉ 8 fatty acids from hexadecanolide 23. Reagents and conditions: (...

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Scheme 4: Synthesis of (A) 2-methyl- and 2-hydroxy-iso-fatty acids 30 and 32, and (B) the ketone 33. Reagents...

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Published 04 Sep 2013

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A practical synthesis of long-chain iso-fatty acids (iso-C12–C19) and related natural products

A practical synthesis of long-chain iso-fatty acids (iso-C₁₂–C₁₉) and related natural products