4 article(s) from Rutjes, Floris P J T
Protonated (or organylated) carbonyl (1) and hydroxy (or organyloxy) carbenium ion (2): two possibl...
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Acid-catalyzed interconversion of carbonyls, hydrates, hemiacetals and acetals.
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Oxacarbenium, oxocarbenium, oxycarbenium and carboxonium ions.
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Beilstein J. Org. Chem. 2018, 14, 2568–2571, doi:10.3762/bjoc.14.233
Assembly of catalyst-functionalized amphiphilic block copolymers into polymer micelles and vesicles...
C–N bond formation under micellar catalyst conditions, no organic solvent involved. Adapted from re...
Suzuki−Miyaura couplings with, or without, ppm Pd. Conditions: ArI 0.5 mmol 3a, Ar’B(OH)2 (0.75–1.0...
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PQS (4a), PQS attached proline catalyst 4b. Adapted from reference . Copyright 2012 American Chemic...
3a) Schematic representation of a Pickering emulsion with the enzyme in the water phase (i), or wit...
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Cascade reaction with GOx and Myo. Adapted from reference .
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Cross-linked polymersomes with Cu(OTf)2 catalyst. Reprinted with permission from .
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Schematic representation of enzymatic polymerization in polymersomes. (A) CALB in the aqueous compa...
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Representation of DSN-G0. Reprinted with permission from .
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The multivalent esterase dendrimer 5 catalyzes the hydrolysis of 8-acyloxypyrene 1,3,6-trisulfonate...
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Conversion of 4-NP in five successive cycles of reduction, catalyzed by Au@citrate, Au@PEG and Au@P...
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Beilstein J. Org. Chem. 2018, 14, 716–733, doi:10.3762/bjoc.14.61
Synthesis of ethyl diazoacetate (1).
Schematic representation of the microreactor setup.
Univariate optimization using 30 s, 15 °C and 1.5 equiv NaNO2 as standard.
2D-Contour plots of the multivariate optimization.
Phase separation using a Flow-Liquid–Liquid-Extraction module (FLLEX) directly coupled to the micro...
Beilstein J. Org. Chem. 2013, 9, 1813–1818, doi:10.3762/bjoc.9.211
General approach for the use of dendritic catalysts in a dialysis bag.
Synthesis of water-soluble iridium catalyst 3.
Synthesis of the desymmetrized bipyridine 8.
Attachment of the adapted ligand 8 to the dendrimers via a multi-isocyanate coupling, followed by i...
Catalytic reductive amination of valine (18) via unfavorable equilibrium reactions in water.
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Formation of 19 catalyzed by the three iridium catalysts.
Reaction setup to perform compartmentalized catalysis.
G3 catalyst 16 activity in dialysis device.
G4 catalyst 17 activity in subsequent runs.
Beilstein J. Org. Chem. 2013, 9, 960–965, doi:10.3762/bjoc.9.110
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