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Beilstein J. Org. Chem. 2026, 22, 344–351, doi:10.3762/bjoc.22.22
Graphical Abstract
Scheme 1: Synthesis of nitroxides 2a–f.
Figure 1: X-ray structure of nitroxide 2d.
Scheme 2: Synthesis of mesyl 3a–f and triazole 4a–f derivatives.
Figure 2: X-ray structures of nitroxides 4a–c.
Scheme 3: Synthesis of alkynones 6a,b.
Scheme 4: Synthesis of vinyl ether 8.
Figure 3: X-ray structures of nitroxides 8 and 9a.
Scheme 5: Synthesis of pyrazole derivatives 9a–c.
Figure 4: Spin–spin coupling constants for reduced nitroxides 9a–c.