2 article(s) from Sakurai, Hidehiro
Structure of the target buckybowls 5a–c.
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Synthesis of dialkoxides 5a–c.
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Proposed mechanism of the formation of 5b and 5c.
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Crystal structure of 5a. a) ORTEP drawing of the crystallographically independent unit with thermal...
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a) Definition of POAV angle (φ). b) Side and c) top view of the molecular skeleton of 1. The double...
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Crystal structure of 5b. a) ORTEP drawing of the crystallographically independent unit with thermal...
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Crystal structure of 5c. a) ORTEP drawing of the crystallographically independent unit with thermal...
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a) UV–vis spectra and b) emission spectra of 1 and dialkoxides 5a–c. For all the spectra, the conce...
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Beilstein J. Org. Chem. 2020, 16, 681–690, doi:10.3762/bjoc.16.66
Columnar packing structures of buckybowls showing (a) unidirectional and (b) opposite structures, i...
Synthesis of pyrenylsumanene (1): (a) Sc(OTf)3 (5 mol %), DIH (100 mol %), CH2Cl2, rt, 2.5 h, yield...
The X-ray crystal structure of 1, showing: (a) top view of the ORTEP drawing with 50% probability, ...
(a) Absorption spectra of 1, 3 and pyrene in CH2Cl2 solution (1.0 × 10−5 M); (b) emission spectra o...
Calculated HOMO and LUMO orbitals and HOMO–LUMO gaps (ΔE) for 1, 3 and pyrene (ωB97XD/6-31G(d)).
Beilstein J. Org. Chem. 2014, 10, 841–847, doi:10.3762/bjoc.10.80
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