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1 article(s) from Sanders, Jeremy K M

Understanding the unexpected effect of frequency on the kinetics of a covalent reaction under ball-milling conditions

Ana M. Belenguer,
Adam A. L. Michalchuk,
Giulio I. Lampronti and
Jeremy K. M. Sanders

Beilstein J. Org. Chem. 2019, 15, 1226–1235, doi:10.3762/bjoc.15.120

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Scheme 1: Solid-state exchange reaction through ball-mill grinding under neat ball-mill-grinding conditions (...

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Figure 1: Solid-state studies reacting 1-1 and 2-2 in an equimolar ratio in the presence of DBU as catalyst t...

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Scheme 2: Schematic representation of a solid + solid mechanochemical reaction. Subscript denote macroscopic ...

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Scheme 3: Simplified reaction equation for the mechanochemical transformation. Note that [AB] is a physical c...

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Figure 2: Reaction profiles for mechanochemical milling according to Equation 4. (a) Kinetic profiles for 30 Hz, 25 Hz,...

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Figure 3: Modelled kinetic profiles for 15 Hz neat milling, with variation in the magnitude of the mixing ter...

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Figure 4: Reaction profiles for LAG mechanochemical milling according to Equation 4. The modelled curves are given for ...

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Published 05 Jun 2019

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