4 article(s) from Schwaneberg, Ulrich
Graphical Abstract
Scheme 1: Left: Mechanism of the olefin metathesis reaction postulated by Chauvin [2]. Right: Potential influenc...
Scheme 2: (i) Ring-opening metathesis polymerization (ROMP), (ii) ring-closing metathesis (RCM) and (iii) cro...
Figure 1: Common anchoring strategies for metal-complex or metal ion incorporation into protein scaffolds.
Scheme 3: Biotinylated GH-type catalysts for conjugation to (strept)avidin and their catalyzed ring-closing m...
Scheme 4: Whole-cell artificial metatheases designed by Ward et al. [47].
Scheme 5: Coupling of GH-type catalysts Ru-4/5/6 to NB4 or NB11.
Scheme 6: Anchoring and refolding of GH-type catalysts Ru-4/5/6 to FhuA.
Figure 2: Top: NB4 (PDB 3WJB); bottom: NB4exp. Highlighted in blue are the additional two β-sheets. Highlight...
Graphical Abstract
Figure 1: Phenylacetylene polymerization of FhuA ΔCVFtev [29] refolded in a polymer or small amphiphilic molecule...
Figure 2: Hydrophobic transmembrane region of FhuA ΔCVFtev [29] stabilized by ≈200 MPD molecules. MPD is illustra...
Scheme 1: Coupling of [Rh]-1 to the open channel protein FhuA ΔCVFtev. SDS, sodium dodecyl sulfate; THF, tetr...
Figure 3: Circular dichroism spectra of 2 refolded in 2-methyl-2,4-pentanediol (MPD, red) and polyethylene–po...
Figure 4: MALDI–TOF mass spectra of apo FhuA ΔCVFtev (red; calculated m/z = 5902.6; found: m/z = 5911.7) and 2...
Graphical Abstract
Scheme 1: Syntheses to Cu(I) complex bearing a NHC ligand.
Scheme 2: Synthesis of Cu(II) terpyridyl complexes.
Scheme 3: Anchoring and refolding of the biohybrid copper complexes.
Figure 1: CD spectra of refolded catalysts 17–19 (red: 17, black: 18, blue: 19).
Figure 2: Temperature-dependent CD spectra of catalyst 17.
Figure 3: MALDI–TOF mass spectra (black: 17, red: FhuAΔCVFtev).
Graphical Abstract
Scheme 1: Biocatalytic n-butane hydroxylation with enzymatic in situ cofactor regeneration.
Scheme 2: Biocatalytic n-octane hydroxylation with enzymatic in situ cofactor regeneration.
Scheme 3: Enzymatic hydroxylation of n-butane (used as liquid) with in situ cofactor regeneration.