An overview on recent advances in the synthesis of sulfonated organic materials, sulfonated silica materials, and sulfonated carbon materials and their catalytic applications in chemical processes

Hashem Sharghi,
Pezhman Shiri and
Mahdi Aberi

Review
Published 01 Nov 2018

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1. Graphical Abstract
2. Figure 1: Different types of sulfonated materials as acid catalysts.
  
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3. Scheme 1: Synthetic route of 3-methyl-1-sulfo-1H-imidazolium metal chloride ILs and their catalytic applicati...
  
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4. Scheme 2: Synthetic route of 1,3-disulfo-1H-imidazolium transition metal chloride ILs and their catalytic app...
  
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5. Scheme 3: Synthetic route of 1,3-disulfoimidazolium carboxylate ILs and their catalytic applications in the s...
  
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6. Scheme 4: Synthetic route of [BiPy](HSO₃)₂Cl₂ and [Dsim]HSO₄ ILs and their catalytic applications for the syn...
  
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7. Scheme 5: The catalytic applications of (C₄(DABCO-SO₃H)₂·4Cl) IL for the synthesis of spiro-isatin derivative...
  
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8. Scheme 6: The catalytic applications of (C₄(DABCO-SO₃H)₂·4Cl) IL for the synthesis of bis 2-amino-4H-pyran de...
  
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9. Scheme 7: The synthetic route of N,N-disulfo-1,1,3,3-tetramethylguanidinium carboxylate ILs and their catalyt...
  
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10. Scheme 8: The catalytic application of 1-methyl-3-sulfo-1H-imidazolium tetrachloroferrate IL in the synthesis...
  
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11. Scheme 9: The synthetic route of 3-sulfo-1H-imidazolopyrimidinium hydrogen sulfate IL and its catalytic appli...
  
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12. Scheme 10: The results for the synthesis of bis(indolyl)methanes and di(bis(indolyl)methyl)benzenes in the pre...
  
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13. Scheme 11: The catalytic applications of 1-(1-sulfoalkyl)-3-methylimidazolium chloride acidic ILs for the hydr...
  
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14. Scheme 12: The synthetic route of immobilized 1,4-diazabicyclo[2.2.2]octanesulfonic acid chloride on SiO₂ and ...
  
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15. Scheme 13: The catalytic application of a silica-bonded sulfoimidazolium chloride for the synthesis of 12-aryl...
  
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16. Scheme 14: The synthetic route of the SBA-15-Ph-SO₃H and its catalytic applications for the synthesis of 2H-in...
  
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17. Scheme 15: The synthetic route for heteropolyanion-based ionic liquids immobilized on mesoporous silica SBA-15...
  
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18. Scheme 16: Some mechanism aspects of SSA catalyst for the protection of amine derivatives.
  
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19. Scheme 17: The synthetic route for MWCNT-SO₃H and its catalytic application for the synthesis of N-substituted...
  
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20. Scheme 18: The sulfonic acid-functionalized polymers (P-SO₃H) covalently grafted on multi-walled carbon nanotu...
  
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21. Scheme 19: The transesterification reaction in the presence of S-MWCNTs.
  
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22. Scheme 20: The synthetic route for the new hypercrosslinked supermicroporous polymer via the Friedel–Crafts al...
  
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23. Scheme 21: The synthetic route for a new microporous copolymer via the Friedel–Crafts alkylation reaction of t...
  
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24. Scheme 22: The synthetic route for sulfonated polynaphthalene and its catalytic application for the amidoalkyl...
  
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25. Scheme 23: The synthetic route of the acidic carbon material and its catalytic application in the etheriﬁcatio...
  
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26. Scheme 24: The synthetic route of the acidic carbon materials and their catalytic applications for the esterif...
  
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27. Scheme 25: The sulfonated MWCNTs.
  
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28. Scheme 26: The sulfonated nanoscaled diamond powder for the dehydration of D-xylose into furfural.
  
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29. Scheme 27: The synthetic route and catalytic application of the GR-SO₃H.
  
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Beilstein J. Org. Chem. 2018, 14, 2745–2770, doi:10.3762/bjoc.14.253

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Solvent-free and room temperature synthesis of 3-arylquinolines from different anilines and styrene oxide in the presence of Al₂O₃/MeSO₃H

Hashem Sharghi,
Mahdi Aberi,
Mohsen Khataminejad and
Pezhman Shiri

Full Research Paper
Published 20 Sep 2017

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1. Graphical Abstract
2. Scheme 1: Synthesis of 3-arylquinolines from anilines and styrene oxide. AMA = Al₂O₃/methanesulfonic acid
  
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3. Figure 1: Investigation of the reusability of Al₂O₃.
  
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Supp. Info

Beilstein J. Org. Chem. 2017, 13, 1977–1981, doi:10.3762/bjoc.13.193

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An overview on recent advances in the synthesis of sulfonated organic materials, sulfonated silica materials, and sulfonated carbon materials and their catalytic applications in chemical processes

Solvent-free and room temperature synthesis of 3-arylquinolines from different anilines and styrene oxide in the presence of Al₂O₃/MeSO₃H

Other Beilstein-Institut Open Science Activities

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An overview on recent advances in the synthesis of sulfonated organic materials, sulfonated silica materials, and sulfonated carbon materials and their catalytic applications in chemical processes

Solvent-free and room temperature synthesis of 3-arylquinolines from different anilines and styrene oxide in the presence of Al2O3/MeSO3H

Other Beilstein-Institut Open Science Activities

Keep Informed

Solvent-free and room temperature synthesis of 3-arylquinolines from different anilines and styrene oxide in the presence of Al₂O₃/MeSO₃H