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1 article(s) from Shibuya, Akito

Electrochemical generation of 2,3-oxazolidinone glycosyl triflates as an intermediate for stereoselective glycosylation

Toshiki Nokami,
Akito Shibuya,
Yoshihiro Saigusa,
Shino Manabe,
Yukishige Ito and
Jun-ichi Yoshida

Letter
Published 28 Mar 2012

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1. Graphical Abstract
2. Scheme 1: Electrochemical conversion of thioglycosides to glycosyl triflates.
  
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3. Figure 1: ¹H NMR spectrum of glycosyl triflate 2a.
  
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4. Scheme 2: Triflic acid mediated isomerization of β-glycoside.
  
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Graphical Abstract

Beilstein J. Org. Chem. 2012, 8, 456–460, doi:10.3762/bjoc.8.52

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