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Beilstein J. Org. Chem. 2018, 14, 182–186, doi:10.3762/bjoc.14.12
Phthalide and fluorinated phthalides (1).
Plausible reaction mechanism for the formation of phthalide 1a.
Synthesis of fluorinated phthalides 1.
Asymmetric synthesis of 1a using a chiral auxiliary.
Catalytic asymmetric synthesis of 1a.
Beilstein J. Org. Chem. 2015, 11, 2661–2670, doi:10.3762/bjoc.11.286
Trifluoromethylation using trifluoroacetate.
Decarboxylative pentafluoroethylation and its application.
Trifluoromethyation with trifluoroacetate in a flow system.
Trifluoromethylation of 4-bromotoluene by [(NHC)Cu(TFA)].
Trifluoromethylation of aryl iodides with small amounts of Cu and Ag2O. aThe yield was determined b...
C–H trifluoromethylation of arenes using trifluoroacetic acid.
CF3Cu generated from chlorofluoroacetate and CuI.
[18F]Trifluoromethyation with difluorocarbenes for PET. aRadiochemical yield determined by HPLC.
Trifluoromethylation with trifluoroacetate and copper iodide.
Preparation of trifluoromethylcopper from trifluoromethyl ketone.
Trifluoromethylation of aryl iodides. aIsolated yield. b1 equivalent each of CF3Cu reagent and 1,10...
Pentafluoroethylation of aryl bromides. aYield was determined by 19F NMR analysis using benzotriflu...
Perfluoroalkylation reactions of arylboronic acids. aIsolated yield. bDMF was used instead of tolue...
Trifluoromethylation with silylated hemiaminal of fluoral.
Catalytic trifluoromethylation with a fluoral derivative.
The scope of Cu-catalyzed aromatic trifluoromethylation. The yield was determined by 19F NMR analys...
Plausible mechanism of Cu-catalyzed aromatic trifluoromethylation .