1 article(s) from Vida, Norbert
- Full Research Paper
- Published 20 Jan 2016
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Graphical Abstract
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Scheme 1: Oxidation of SF5-anisole and phenol. 19F NMR yields are shown (isolated yields in parentheses).
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Scheme 2: Proposed mechanism for the formation of 3 and 4 from SF5 aromatics 1 and 2.
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Scheme 3: Oxidation of anisole 10 and phenol 11. 19F NMR yields are given.
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Scheme 4: Synthesis of para-benzoquinone 12 and oxidation to maleic acid 4. 19F NMR yields are shown, in pare...
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Scheme 5: Catalytic hydrogenation and Diels–Alder reaction of benzoquinone 12.
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Figure 1: Optimized geometries of transition states of Diels–Alder reaction of cyclopentadiene with 12. Selec...
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Scheme 6: Decomposition of 3 in water.
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Scheme 7: Formation of acids 5, 18 and 19 from lactone 3.
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Scheme 8: Synthesis of maleic anhydride 20 and Diels–Alder adducts 21.
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Scheme 9: Reaction of maleic acid 4 with diazomethane.
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Scheme 10: Decarboxylation of maleic acid 4 to acrylic acid 23 in DMSO and the preparation of deuterium labell...
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