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1 article(s) from Xu, Xingyu

Halogen-bonding-induced diverse aggregation of 4,5-diiodo-1,2,3-triazolium salts with different anions

Xingyu Xu,
Shiqing Huang,
Zengyu Zhang,
Lei Cao and
Xiaoyu Yan

Beilstein J. Org. Chem. 2020, 16, 78–87, doi:10.3762/bjoc.16.10

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Figure 1: 1,2,3-Triazole based XB donors: 1,2,3-triazole A, 1,2,3-triazolium B, 1,2,3-triazolylidene C and di...

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Scheme 1: Synthesis of 4,5-diiodo-1,3-dimesityl-1,2,3-triazolium with iodide, Mes: 2,4,6-Me₃C₆H₂.

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Scheme 2: Synthesis of 4,5-diiodo-1,3-dimesityl-1,2,3-triazolium with different anion.

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Figure 2: Packing structure of 2-I (top), 2-Br (middle) and 2-Cl (bottom). Hydrogen atoms have been omitted f...

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Figure 3: Packing structure of 2-BF₄. Hydrogen atoms have been omitted for clarity.

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Figure 4: Packing structure of 2-OAc. Hydrogen atoms and solvent molecules have been omitted for clarity.

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Figure 5: Packing structure of 2-TFA. Hydrogen atoms and disorder of fluorine atoms have been omitted for cla...

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Figure 6: Packing structure of 2-I^.1.5I₂. Hydrogen atoms have been omitted for clarity.

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Figure 7: Packing structure of 2-I^.3.5I₂. Hydrogen atoms have been omitted for clarity.

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Figure 8: Packing structure of 2-BF₄^.0.5bpy. Hydrogen atoms and dichloromethane have been omitted for clarity....

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Figure 9: 1,2,3-Triazole-based halogen model calculation: electrostatic potential surfaces mapped on total de...

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Published 13 Jan 2020

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