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Beilstein J. Org. Chem. 2024, 20, 1421–1427, doi:10.3762/bjoc.20.124
Graphical Abstract
Scheme 1: Preparation of cyclic oligoglucosamines a) via intramolecular glycosylation and b) via polyglycosyl...
Scheme 2: Proposed reaction mechanism of the formation of 1,6-anhydrosugar 7.
Scheme 3: Electrochemical polyglycosylation of monomer 14 with a 2,3-oxazolidinone protecting group.
Scheme 4: Proposed reaction mechanism of the formation of cyclic trisaccharide 19a.
Scheme 5: Influence of the functional group in position C-2 on the formation of the cyclic product.
Beilstein J. Org. Chem. 2022, 18, 1154–1158, doi:10.3762/bjoc.18.119
Figure 1: (a) Cyclic voltammograms of a BDD electrode in MeCN solution containing cumene (1; 5 mM) and Et4NClO...
Figure 2: Proposed reaction mechanism of electro-conversion of cumene (1) into acetophenone (3).