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Beilstein J. Org. Chem. 2021, 17, 551–557, doi:10.3762/bjoc.17.49
Graphical Abstract
Scheme 1: Origin of the reaction design.
Scheme 2: Substrate scope of disulfides.
Scheme 3: Substrate scope of unactivated alkenes.
Scheme 4: Control experiments.
Scheme 5: Proposed mechanism.
Beilstein J. Org. Chem. 2020, 16, 1225–1233, doi:10.3762/bjoc.16.106
Figure 1: Bioactive pyrrolo[2,1-a]isoquinolines and hexahydropyrrolo[2,1-a]isoquinolines.
Scheme 1: [3 + 2] Cycloaddition with amino esters or amino acids.
Scheme 2: Scaffolds derived from the initial [3 + 2] adducts.
Scheme 3: [3 + 2] Cycloaddition with amino esters or amino acids. Conditions: 1:3:4 (1.2:1:1.1), Et3N (1.5 eq...
Scheme 4: Synthesis of pyrrolo[2,1-a]isoquinolines 9. Reaction conditions: 5 (0.5 mmol, 1 equiv), 7 (3 equiv)...
Scheme 5: Synthesis of pyrrolo[2,1-a]isoquinolines 11. Reaction conditions: 6 (0.5 mmol, 1 equiv), 7 (3 equiv...
Scheme 6: Synthesis of pyrrolo[2,1-a]isoquinolines 12. Reaction conditions: 5 or 6 (0.5 mmol, 1 equiv), cinna...
Scheme 7: Plausible mechanism for the synthesis of 9a.
Beilstein J. Org. Chem. 2018, 14, 869–874, doi:10.3762/bjoc.14.73
Scheme 1: Synthetic routes of CEPDO and CBPDO.
Figure 1: Structures and molecular orbitals of (a) CEPDO and (b) CBPDO.
Figure 2: UV–vis absorption and photoluminescence spectra in DCM solution (1 × 10−5 M and 1 × 10−6 M, respect...
Figure 3: Cyclic voltammograms for CEPDO and CBPDO in DCM solution.
Figure 4: DSC and TGA curves of CEPDO and CBPDO.