1 article(s) from von Hahmann, Cortney N
Graphical Abstract
Scheme 1: Synthesis of 2-pentafluorosulfanylaldehydes by addition of SF5Cl to enol ethers.
Scheme 2: Reaction of pentafluorosulfanylaldimines with benzyloxyketene.
Scheme 3: Preparation of ethyl pentafluorosulfanylpyruvate and formation of the corresponding β-lactam.
Figure 1: The 1,2-lk stereochemistry of 7a as determined by single crystal X-ray diffraction. Thermal ellipso...
Scheme 4: Influence of the SF5 group on the initial attack of the ketene on the imine nitrogen (A) and on the...
Figure 2: The stereochemistry of 7c, 1,2-lk,lk (Si, Si-S), as determined by single crystal X-ray diffraction ...