1 article(s) from von Hahmann, Cortney N
- Letter
- Published 27 Nov 2013
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Graphical Abstract
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Scheme 1: Synthesis of 2-pentafluorosulfanylaldehydes by addition of SF5Cl to enol ethers.
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Scheme 2: Reaction of pentafluorosulfanylaldimines with benzyloxyketene.
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Scheme 3: Preparation of ethyl pentafluorosulfanylpyruvate and formation of the corresponding β-lactam.
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Figure 1: The 1,2-lk stereochemistry of 7a as determined by single crystal X-ray diffraction. Thermal ellipso...
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Scheme 4: Influence of the SF5 group on the initial attack of the ketene on the imine nitrogen (A) and on the...
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Figure 2: The stereochemistry of 7c, 1,2-lk,lk (Si, Si-S), as determined by single crystal X-ray diffraction ...
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