Beilstein J. Org. Chem.2010,6, No. 13, doi:10.3762/bjoc.6.13
nucleic acids (TINA) [27][28], and by our group for fluorescent DNA base substitutions by ethidium [29][30], indole [31][32], thiazole orange [33][34], perylene bisimide [35][36] and phenothiazine [37]. This 2′-deoxyriboside substitution provides high chemical stability and conformational flexibility for
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Graphical Abstract
Scheme 1:
Chirality of C-3 of natural 2′-deoxyribofuranosides (left) in comparison with the acyclic D-threoni...
Beilstein J. Org. Chem.2009,5, No. 6, doi:10.3762/bjoc.5.6
characterized a donor-acceptor dyad system involving tetrathiafulvalene (TTF) as electron donor attached by a flexible spacer to perylene derivatives as electron acceptor [5]. They have shown that the fluorescence of the tetrathiafulvalene–perylene derived dyad can be reversibly modulated by the transformation