Beilstein J. Org. Chem.2021,17, 2028–2050, doi:10.3762/bjoc.17.131
substituted anthracenes by the regioselective oxidative benzannulation of 1-adamantyl-1-naphthylamines 10 with internal alkynes 11 (Scheme 2) [35]. To the best of our knowledge, this was the first successful example of rhodium-catalyzed benzannulation reactions of N-adamantyl-1-naphthylamines. Reactions of 10
oxidative benzannulation reactions of 1-adamantoyl-1-naphthylamines with internal alkynes.
Gold/bismuth-catalyzed cyclization of o-alkynyldiarylmethanes.
[2 + 2 + 2] Cyclotrimerization reactions with alkynes/nitriles in the presence of nickel and cobalt catalysts.
Cobalt-catalyzed [2 + 2 + 2
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Graphical Abstract
Figure 1:
Examples of anthracene derivatives and their applications.
Beilstein J. Org. Chem.2018,14, 2090–2097, doi:10.3762/bjoc.14.183
system. Moreover, a series of biologically relevant fluorine-aryl ethers were easily obtained under mild reaction conditions after the removal of the directing group.
Keywords: alkoxylation; C–H activation; cobalt catalysis; 1-naphthylamines; secondary alcohols; Introduction
Aryl ethers are common
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Graphical Abstract
Figure 1:
Strategies for cobalt-catalyzed alkoxylation.