Efficient carbon-Ferrier rearrangement on glycals mediated by ceric ammonium nitrate: Application to the synthesis of 2-deoxy-2-amino-C-glycoside

• Alafia A. Ansari,
• Y. Suman Reddy and
• Yashwant D. Vankar

Beilstein J. Org. Chem. 2014, 10, 300–306, doi:10.3762/bjoc.10.27

• -glycosides; carbon-Ferrier rearrangement; ceric ammonium nitrate; 2-deoxy-2-aminoglycosides; Overman rearrangement; Introduction The growing significance of C-glycosides can be attributed to their potential use as inhibitors of carbohydrate-processing enzymes [1][2][3], their extraordinary stability