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Search for "3,3,3-trifluoropropenyl" in Full Text gives 2 result(s) in Beilstein Journal of Organic Chemistry.
Development of a fluorogenic small substrate for dipeptidyl peptidase-4
Beilstein J. Org. Chem. 2017, 13, 2690–2697, doi:10.3762/bjoc.13.267
- , Kashiwara, Osaka 582-8582, Japan 10.3762/bjoc.13.267 Abstract A series of aniline and m-phenylenediamine derivatives with electron-withdrawing 3,3,3-trifluoropropenyl substituents were synthesized as small and chemically stable fluorescent organic compounds. Their fluorescence performances were evaluated
- push–pull system, which has a single benzene ring substituted by both electron-donating and electron-withdrawing groups [15][16][17]. We focused on the 3,3,3-trifluoropropenyl (TFPE) group, which is an electron-withdrawing substituent that is free of oxygen atoms, which would form hydrogen bonds in
Oxidative 3,3,3-trifluoropropylation of arylaldehydes
Beilstein J. Org. Chem. 2013, 9, 2417–2421, doi:10.3762/bjoc.9.279
- reaction involves oxidative 3,3,3-trifluoropropylation of an arylaldehyde to afford 4,4,4-trifluoro-1-arylbutan-1-one. Keywords: cesium fluoride; organo-fluorine; 1,3-proton shift; trifluoromethyl; 3,3,3-trifluoropropenyl; Introduction Trifluoromethyl groups are an essential motif in pharmaceuticals
- used in place of (3,3,3-trifluoropropynyl)lithium, which can add to carbonyl compounds and couple with aryl halides through a zinc intermediate. For the 3,3,3-trifluoropropenyl synthon Yamazaki et al. reported the use of 2-(trifluoromethyl)-1-(phenylsulfenyl)vinyltrimethylsilane for the addition to
- aldehydes in the presence of fluoride anion [29]. Recently, Prakash et al. [30] reported the synthesis of β-trifluoromethylstyrenes through a Heck coupling reaction of aryl iodides with 1-iodo-3,3,3-trifluoropropane, allowing a direct introduction of 3,3,3-trifluoropropenyl groups to aromatic rings
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