Beilstein J. Org. Chem.2011,7, 9–12, doi:10.3762/bjoc.7.2
above room temperature, and in chlorinated solvents they undergo rearrangement to form the more stable N-(tert-butylthio)-tert-butylsulfonamide.
Keywords: chlorinated solvents; N-(tert-butylthio)-tert-butylsulfonamide; tert-butylsulfinamide; thermal rearrangement; Introduction
Over the past decade, an
room temperature and in chlorinated solvents.
Experimental
See Supporting Information File 1 for full experimental data.
tert-Butylsulfinamide.
N-(tert-butylthio)-tert-butylsulfonamide.
ORTEP diagram of 3.
Synthesis of acid amide.
Chemical synthesis of 3.
Synthesis of tert-butylsulfanyl chloride